Bromine Trifluoride: Reacts vigorously. Bromine trifluoride is an interhalogen compound with the formula BrF 3.It is a straw-coloured liquid with a pungent odor.  It is soluble in sulfuric acid but reacts violently with water and organic compounds. Chemical Equilibria in the Gaseous System Bromine-Bromine Trifluoride-Bromine Monofluoride1. Journal of Fluorine Chemistry 129 Elsevier Sequoia S.A., Lausanne - Printed in Switzerland THERMOCHEMISTRY OF FLUORINE COMPOUNDS. It is soluble in sulfuric acid but reacts violently with water and organic compounds. The chart below shows the calculated isotope pattern for the formula BrF 3 with the most intense ion set to 100%. 79.9 + (35.45*3) = 186.25. (USCG, 1999). Solidifies at 48°F. Containers exposed to prolonged heat may violently rupture and rocket. The heat of vaporization was estimated from the following equation which is based upon the Clausius-Clapeyron relation. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009. Bromine trifluoride is a highly toxic and corrosive fluoride of bromine with chemical formula BrF 3. Bromine trifluoride is an interhalogen compound with the formula BrF 3.It is a straw-coloured liquid with a pungent odor. The chemical has a pungent odor. If 28.5 grams of bromine trifluoride react to form 16.6 grams of bromine, how many grams of fluorine must simultaneously be formed? Use caution: Liquids with this reactive group classification have been TOXIC LEVEL EXPOSURE TO SKIN TISSUES CAUSES HYDROFLOURIC ACID BURNS AND SKIN LESIONS RESULTING IN TISSUE DESTRUCTION AND EVENTUAL SCARING. CAS number. The element is liberated by halogen exchange, using chlorine gas to oxidise Br − to Br 2. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Fluoride (hydrofluoric acid) gas will be created in 1.2 minutes. The products involved fine chemicals, pharmaceutical intermediates, dye intermediates, cosmetic raw materials and so on. Full Record; Other Related Research 12524-63-9 . Decomposition: Write Equations 1 answer below » Write a balanced equation for the decomposition reaction described, using the smallest possible integer coefficients. Very toxic by inhalation and corrosive to metals and tissue. decomposition process of intercalated graphite compounds on the crucible surface. Mixing with the following hydrogen-containing substances is likely to cause a fire or explosion: acetic acid, ammonia, benzene, ethanol, 2-pentanone, hydrogen, hydrogen sulfide, methane, cork, grease paper , wax. Bromine trifluoride decomposes into bromine and fluorine upon the absorption of 300.8 kJ of heat for each mole of bromine trifluoride decomposed. Frozen bromine trifluoride reacts violently with toluene at -80 deg C. ... and subsequent nitration and decomposition of nitrocresols. Bretherick, L. Handbook of Reactive Chemical Hazards. Contact with liquid or vapor causes severe burns of eyes and can cause ulcers and blindness. Solid-Liquid Phase Equilibria in the Condensed System Bromine-Uranium Hexafluoride. It was discovered by Paul Lebeau in 1906. Chemical Equilibria in the Gaseous System Bromine-Bromine Trifluoride-Bromine Monofluoride1. (1969), http://www.chammascutters.com/en/downloads/Bromine-Trifluoride-MSDS.pdf, https://en.wikipedia.org/w/index.php?title=Bromine_trifluoride&oldid=985522573, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, dangerously sensitive to water, source of, This page was last edited on 26 October 2020, at 13:03. Handling, Storage, and Precautions: Use in a fume hood; BrF 3 can be stored in stainless steel or Teflon containers. 4th ed. trifluoro-λ³-bromane . BrF3 ( BROMINE TRIFLUORIDE ) is Polar I'll tell you the polar or nonpolar list below. This section provides a listing of alternate names for this chemical, is a professional manufacturing enterprise integrating R&D, production and sales. BROMINE TRIFLUORIDE is a very reactive oxidizing agent. Other . The chemical formula for this compound is BrF3. References. It is used to produce uranium hexafluoride (UF 6) in the processing and reprocessing of nuclear fuel. Accelerates the burning of combustible material. Behavior in Fire: Forms very toxic and irritating fumes. The heats of formation of stannic and antimonic flourides were found by dissolving tin and antimony in a bromine triflouride-bromine mixture. It is a straw-colored liquid. Journal of the American Chemical Society 1957, 79 (6) , 1320-1323. Quincy, MA: National Fire Protection Association, 2002., p. 491-37 Experimental details are in the following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. Bromine is the third halogen, being a nonmetal in group 17 of the periodic table. Element % Br: 58.37: F: 41.63: Isotope pattern for BrF 3. Kenneth A. Wilde, Bruno J. Zwolinski, Ransom B. Parlin. It is a straw-coloured liquid with a pungent odor. May intensify fire; oxidizer. About Bromine trifluoride; 2 803 kilograms [kg] of Bromine trifluoride fit into 1 cubic meter; 174.98557 pounds [lbs] of Bromine trifluoride fit into 1 cubic foot; Bromine trifluoride weighs 2.803 gram per cubic centimeter or 2 803 kilogram per cubic meter, i.e. For the BrF 3 Lewis structure, calculate the total number of valence electrons for the BrF 3 molecule. Enter the reaction without the energy term: check_circle. , The liquid is conducting, owing to autoionisation:, Fluoride salts dissolve readily in BrF3 forming tetrafluorobromate:, Except where otherwise noted, data are given for materials in their, A. J. Edwards and G. R. Jones.
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